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They have unique properties that give important biological or medical properties
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- suggested using an enamine intermediate because it's a weaker base (it's neutral!!) and so more likely to act as a Michael donor (1,4- addition)
- HCN is highly toxic, so KCN/HCl is typically employed. Nitriles are precursors to amines/carboxylic acids
- more reactive than ethers due to the presence of the larger, more polarizable S atom. Unlike ethers, sulfides will undergo attack on an alkyl halide