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the enolate typically constitutes only a small fraction of the equilibrium mixture
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- at least one of the reagents (or catalyst) must be chiral, the Sharpless catalyst forms such a chiral complex with an allylic alcohol
- electrophilic carbon atoms. The beta-C is electrophilic because it shares the δ+ of the carbonyl C (resonance).
- enolates. Kinetic product forms faster, thermodynamic is more stable (more substituted c=c; favored at high T)